Yes, sa zone valve motor stuck in the on position would keep the boiler 'on demand' to check this, with the time clock powered off, check the little lever/paddle on the zonevalve, if it is loose (slides from side to side) with the clock 'not' calling for heat, then it may be stuck, or possibly one of your thermosats may be stuick 'on' turn them all to zero too
I have never yet come across a timeclock calling for heat when off (first time for everything though)