we put in a back boiler when doing up the house 2 years ago.
there was a normal fireplace there and a new small oil stove in the kitchen.
best thing we ever did. we upgraded our water tank also - not sure what size but double the normal. We light a fire most nights. and it keeps the house nicely warm , but not tropic. And the next morning - tons of hot water for the power shower - super.
it will have to be an open system to take a back boiler - and talk to your plumber about "pitching", thats where the hot water gets pumped out into the expansion tank. The pipe work needs to be A1.
k