Davy, was thinking about your answer to this, ie, system water mixing in the cylinder through a hole in the coil....
If it's on the cold taps only then maybe this is a so called 'semi-sealed' system feeding into sytem water directly from the domestic water tank (have seen it too many times!) and the non-return valve may have failed allowing system water to mix into the tank, again as you said giving the yellow color.......
Davy IMHO semi sealed are done for one reason only and that is to cover up shoddy plumbing and possible leaks
I agree with the sentiment to remove and replace with filling loop and gauge but in the past when I have done it have found systems leaking like a strainer. And usually underfloor somewhere
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