Your wife has 8 years now, and needs min 10 for any UK pension.
She has the opportunity to buy 13 back years, plus 11 forward, (Max possible pension = 32/35th)
BUT the 06/07 - 18/19 opportunity will be lost after this April
While 24/25 will be available until 2031, 25/26 until 2032 etc (unless they change the 6 year rule)
It may be an idea to forget about 24/25 for now, and buy back at least 2 (to get to 10 years) plus as many of the early years as affordable at this point in time. The 52 week years are slightly cheaper than 08/09 and 14/15
Best of Luck!