Rental income itself is not pensionable. Only your earned income is pensionable. However, if you're not claiming your full allowances of tax relief in respect of your earned income, you can still make an extra AVC against your earned income which would have the same effect in terms of reducing your tax bill.
Assuming that you have one source of earned income, you can either contribute to the pension scheme's AVC plan or choose your own AVC PRSA from [broken link removed].