If she is in receipt of Rent Supplement at your address, then you would have had to complete part of her Rent Supplement application form when she applied. You would have received a letter from the HSE requesting your PPSN when her claim was awarded.
If you didn't sign a form or receive a form from HSE, is it possible that your sister claimed Rent Supplement from a different address in the past and hasn't told the CWO that she's moved?
If you are the named landlord on her Rent Supplement application, details of the amount paid in Rent Supplement, as well as your name and address are submitted to Revenue each year.