This should be simple enough to sort yourself.
Firstly the single glazing will be loosing a huge amount of heat. Get yourself a set of curtains with a heavy thermal lining, usually you buy the lining itself. Put them up and you should see a massive differance. Also put a sheet of paper in the window and close it, just about 10mm, if you can pull it out easily the window is also not sealing correctly and will all the time be allowing cold air to flow into the room. You will be able to reuse the curtains when you get your double glazing.
Nothing cools a room like cold draughts. Ensure there are no gaps between the frame and window. Reseal on the inside if required.
Radiators:
The system if 25 years old could have several issues.
Rads may be undersized, use a rad calulator to determine the required size in BTUs for you room and them compare to a a rad spec sheet such as can be found on quinn rads or biasi.ie.
If undersize you can only replace with a larger rad. Assuming your boiler is sized correctly for the house the only issue is that is will be of a lower efficiency and costing more to run.
The rads may be sludged up after 25 years, a powerflush of the system may do wonders, they may also need bleeding to release air in the rads, check for cold spots near the end of the rads (sludge) or the top (air).
If you have not, put 300mm of insulation in the attic asap. Hot air rises so if you stop it at attic level it will back up per say to the ground floor a lot quicker.
Finally draughts, these are your enemy. My technique was to light a roaring fire, cover the vent to force the air to be sucked from else where but remember about carbon monoxide so make sure you have a mox alarm and them go room to room with a gas fire lighter like you get from bic, I ran this around doors, skirting to determine where the draughts were comming from, in my case, it was under the skirting which I then sealed to the floor and from one room in particular which had a window with bad hinges, this part can be very time consuming but put in the time and you will reap the rewards quickly as even when unlit an open fireplace will always be drawing air in. But you need to cover the room vent to force it to draw from elsewhere.
Regards