Get a hold of a plumber, sooner rather than later. Chances are you have a leaking pipe which is causing the pressure to drop.
The rad not working might just be due to a closed value. Are you able to turn the value on the rad itself, sometimes the pipe joining the rad is not straight and will not operate correctly, this is a small job which could be done at the same time as the boiler pressure job.
Have you tried asking the last owners, maybe there is some history there, and a word with them might save your Plumber alot of time.