Do yo have water leaking at the pipe on the outside wall behind your boiler?
If so, the prv valve will need replacing, but that is only part of the story, it must have activated for a reason.....
1) maybe your pressure vessel has failed, needs recharging, or needs the shreader valve changing, or is possibly too small fro the system (but if too small this would be a constant problem)
2) your filling loop maybe passing sending your pressure to high
where are you located?