As DGOBS correctly says, fit a frost stat, normally set to +4C, but also fit a pipe stat to flow pipe from boiler set to 30C. This will turn off the boiler when water temp reaches 30C. If your system is zoned, i.e. motorized zone valves, then also fit an automatic bypass valve between the positive side of the circulating pump and the return, set to approx 400mbar. The frost stat will require its own permanent live to power as the burner live will only be live when the timeclock allows it.