Yes of course you can.
But as she has a medical card she doesn't need a policy to cover any outpatient things, with the exception of if she chooses to see a consultant privately. Therefore, she really only needs one that covers hosspital stays.
I have a medical card myself and am on VHI One Plan 250. It covers hospital stays and some outpatient benefits, subject to a total policy excess of 250 euro per year. I reduced my cover to cut the cost this year but haven't been doing so well healthwise so with opaying the excess brings me near the cost of One Plan Sport which I was on before